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Analysis of ionic equilibrium, electrode potentials, and electrochemical cells.
| Part | Chapters (selected) | Main Themes | |------|----------------------|-------------| | | 1. Review of Wavefunctions 2. Perturbation Theory (time‑independent & time‑dependent) 3. Variational Methods 4. Molecular Orbital Theory (HF, post‑HF) | Derivation of key equations, practical computational approaches, and illustrative examples (H₂, water). | | II. Statistical Mechanics | 5. Ensembles Revisited 6. Phase Transitions & Critical Phenomena 7. Monte‑Carlo & Molecular Dynamics 8. Quantum Statistics (Bose‑Einstein, Fermi‑Dirac) | Emphasis on modern simulation techniques, finite‑size scaling, and connections to experimental observables. | | III. Thermodynamics of Real Systems | 9. Real‑Gas Equations of State 10. Solution Thermodynamics (activity coefficients, electrolytes) 11. Chemical Reaction Equilibria in Complex Media | Provides a bridge between ideal theory and the messy reality of industrial processes. | | IV. Spectroscopy & Photochemistry | 12. Advanced Vibrational Spectroscopy (IR, Raman, 2D‑IR) 13. Electronic Spectroscopy (UV‑Vis, fluorescence, ultrafast pump‑probe) 14. Photochemical Reaction Dynamics | Focuses on interpreting spectra with quantum‑mechanical models and modern laser techniques. |
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