Ipzz-266 (FHD · HD)
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exhibited a glass transition (T_g) at 112 °C, a modest increase relative to pristine P3HT (≈ 78 °C), consistent with the stiffening effect of ionic side‑chains.
¹Department of Chemical Engineering, University of Northbridge, USA ²Institute of Materials Science, Universidad de la Costa, Spain ³School of Chemistry, Tsinghua University, Beijing, China ⁴Center for Nanotechnology, Indian Institute of Technology, Mumbai, India
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Broadband dielectric spectroscopy revealed a plateau in the real part of the conductivity (σ′) above 10 kHz. At 80 °C, σ_ion = 3.1 × 10⁻³ S cm⁻¹ (activation energy E_a ≈ 0.18 eV). The frequency‑independent region widened with temperature, indicating a Vogel–Fulcher–Tammann (VFT) behavior typical for ion‑conducting polymers.
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In the bustling streets of Tokyo, where neon lights dance across the rain-soaked pavements, two individuals lived parallel lives, their paths destined to intersect in a moment that would change their existence forever. At 80 °C, σ_ion = 3
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